As a starting point you might check exactly what your personal insurance policy covers.
This whole thing sounds like a bad idea. Fun, of course, but there might be more to it than you read on muzzle loading sites.
Buy a gun from some Spanish or Italian maker that has a good idea what they are doing. Modify it to suit your idea of style'
Well, what a dumb thing to say! You are sure a-gonna make your own!
Steel. At least do not use any free machining steel. Sometimes called "resulfurized" or "leaded". Some have phosphorus added. Never, ever use a steel called "12L14L Yeah, a lot of people do but I have an unpleasant list of shooters whose bodies have been modified by using barrels made of 12L14 steel.
Strength is nice but toughness and ductility are more important when something goes wrong. Best choice is to have something called "Rifle Quality Steel" or, I think, "Gun-barrel Quality Steel" Chances are about non-existant of finding such outside of a custom MODERN gun barrel maker's shop. In practice best you might do is get some annealed 4130 or 4140 bar (not ever tube or pipe) and drill it out. 8620 may also be OK
I made my first pistol I think in 1959. Used a modern .45 ACP barrel with my own half-a---- breechplug. Didn't shoot it much. But it was fun. First rifle made couple years later, used a modern .44 cal blank. Happily, modern made muzzle loading barrels were not yet available.
Studied metallurgy in collage, worked my whole career as a metallurgist. Heat-treated steel, stainless steel and finally special high temperature alloys were my thing. More to the point here, I was also an expert witness for the plaintiff in several muzzle loading barrel failures.
Do you have any experience with 34CrNiMo6 in quenched and tempered condition? I’ve read multiple steel charts regarding mechanical properties such as high tensile strength etc. and it seem to me that this steel is a good option. For example 4140 has 655 Mpa in tensile strength and 414 Mpa in yield strength in annealed condition.
34CrNiMo6 (in quenched and tempered conidition which is what I’ll use anyway) has 900-1100 MPa tensile strength and minimum 700 MPa yield strength. However, in quenched and tempered condition 4140 has 1075 Mpa tensile strength and 986 Mpa yield strength according to this site
SAE AISI 4140 Steel Properties, Material Heat Treatment, Rockwell Hardness - The World Material
According to this site 8620 steel doesn’t exist in +QT condition and has much lower values
AISI SAE 8620 Steel Properties, Chemical Composition, Equivalent, Heat Treatment - The World Material
In +QT condition 4130 has 1040 Mpa tensile strength and 979 Mpa yield strength. 34CrNiMo6 seem to be harder than the steels you mentioned though, with a HB value of 275-335.
Btw I think I’ll go down to caliber .50 which will reduce the weight of the ball to 177 grains and I’ll also reduce the maximum charge to 70 grains.
Regarding the chemical composition. In the resource for minimum wall thickness and steel that was linked to earlier, it’s stated that: ”For firearms, certain of the alloy ingredients call for particular attention: The maximum content of the elements phosphorus and sulphur must be 0,025 - 0,035%. A high degree of steel purity sought after from the point of view of elasticity is linked with some loss of machineability. In this connection, ISO Standards provide in each case a maximum and minimum percentage for sulphur content.”
When I look at the steel you mentioned and compare with 34CrNiMo6 I don’t see that there’s a different here, atleast not that disfavour 34CrNiMo6. According to this site
https://www.steel-grades.com/Steel-Grades/Special-Alloy/4140.html 4140 have P= 0.04% and S= 0.045%.
For 34CrNiMo6: P= 0,015% and S= 0,030% as typical composition. The maximum value I found was P=0,035. It was harder to find a max value on S but it seem to be within the range 0,020-0,035 (how does higher or lower sulfur content affect a gun barrel?)
However, it’s possible that the 4140 resource on this is too versatile and that the specific kind of 4140 that’s used in barrels has lower values.