The issue of CB revolver chamber diameter, bore diameter, and groove diameter has been punted around for some time.
In my mind, for best accuracy, the issue is the relationship of the chamber diameter to the barrel's groove diameter. If the ball, as forced into the chamber, is less than the groove diameter, it likely would not properly engage the rifling in the barrel. Chamber diameters are fairly easy to measure, groove diameters, especially with an odd number, require special equipment.
One can make a guess at the groove diameter with an expanding plug gage with small enough fingers to just fit the grooves. Most of my replica CB revolvers have groove diameters same/slightly smaller than the chamber. They shoot good enough for me, but skilled marksmen may want better results.
Don't know if soft lead ball obturates enough to fully engage rifling, or if it even matters.