Remove the drum cleanout screw & also the nipple. Run a pipecleaner soaked in hot soapy water thru the cleanout & see if you get any black residue - if so, keep cleaning until you get no more black residue. If this gun has been fired a lot, there may be more stubborn carbon residue baked into the flash channel, and you may want to hand push in successively larger wire twist drill bits, to use as a scraper & not as a metal borer to clean out any stubborn accumulation.
Especially with Pyrodex, holding the barrel vertical & tapping it a few times with a wooden dowel, tool handle or even the heel of your shoe, a couple of times to settle in the powder, then firmly seat the ball & you should see improved ignition.
If there's still some delay, consider a #11 nipple & the new Hotter Remington caps, or CCI Magnums. I use both interchangeably & just base my preference on price (cheaper IS better).