Use real black powder, not the subs. If you are into " smokeless powder" you should have a chronograph. Use IT! With any double gun, you have to work up separate loads for each barrel. You have two different guns of the same caliber, mounted on the same stock, in effect. Don't think the same load is going to give the best accuracy in both barrels. Don't expect the barrels to be regulated to hit the same point of aim, with any load.
Google the gun on the net to see if there are any loads recommended by the factory.
I suggest starting by measuring the bores of both barrels, as well as the groove diameter. The Bore diameter is the distance from one land to another land opposite it. The Bore diameter will tell you what size ball( or bullet) will work in the barrels. They may be different! The Groove depth gives you an idea how thick a cloth patching material you will need to shoot well.
I recommend beginning with using a PRB in the barrels. Most .50s will shoot the .490 RB fairly well. Some shoot better with .495", or .500" balls. You want a ball that is at least .010" smaller in diameter than the bore diameter, for most purposes. Patch thickness has to be chosen with the understanding that a cloth patch compacts when wet, to less than half it dry thickness, so that if you have a groove that is .008" you are probably going to need a patch that is .018, or .020" thick to make the gun shoot well.
Invest $15.00 to buy Dutch Schoultz's Black Powder Accuracy System. Its well worth the money and will help you understand how to work up accurate loads for your rifle.
http://www.blackpowderrifleaccuracy.com/
I recommend using a RB over a bullet for starters, because it allows you to do a lot of shooting for a lot less money, and you do need to shoot this gun a lot to get to know its triggers, hammer fall, balance, and pointing characteristics. RB loads also tend to recoil less, and you don't need recoil when learning the gun.
Try a load of 50 grains of FFFg powder. This will probably not give you the most accuracy, but it will put you on paper at 25 yards, and at 50 yards. work up and down by 5 grain increments to find out what load seems to be the most accurate. Typically, you will find an accurate 50 yard load at 55-65 grains for a .50. Work with each barrel separately. Use separate targets so you don't confuse yourself as to which load works in which barrel. When you have the most accurate load for each barrel worked out, THEN you can attempt to see if you can get them to hit close to the same POA.
You indicate that you want to shoot Maxiballs out of this gun. Why? This is not a .50 caliber Sharps rifle, and never will be. You need to know what the rate of twist of the rifling is, before you try finding a conical bullet to fire in the barrels. The faster the twist of the rifling, the heavier a bullet can be fired, generally. But again, this is not a Sharps Buffalo gun. Its still a Black powder muzzle loading rifle. You get TWO shots, and then its going to take you time to reload the gun. How fast you can reload depends on you. I would not use such a gun to hunt dangerous game unless I had someone backing me up with a high powered rifle.
Penetration of live tissue depends more on the weight of a projectile than its velocity. Just do penetration testing with any bullet, using light and heavy loads to see what I mean. You don't get more penetration using MORE POWDER! You get it using a heavier bullet. With RBs, you can improve penetration a bit by casting the balls from an alloy of harder lead. Adding tin, or antimony, or both will reduce the ball's flattening on impact, giving better penetration, but at the sacrifice of a larger wound channel through the tissue that a flattening ball makes going through vital organs. Mind you, you still have a 1/2 inch hole going through the animal, but using a soft lead RB will create a much larger hole.If you are new to BP shooting, that is a difficult concept to accept, as it seems counter-intuitive to everything you have worked with using modern smokeless powder cartridges and jacketed bullets, fired at high velocity.
Best wishes. :thumbsup: