This may be the posting by Paul that you were looking for. Paul was a very knowlegable man and one from whom we could learn a lot. I miss him, he was a good friend.
If the formula that people are referring to here is he one that Charles Davenport promolgated back in the late 40s, THAT FORMULA has NOTHING to do with " Maximum Powder BURN"-- whatever that is.
The Davenport formula- 11.5 grains of Black powder per cubic inch of bore-- has to do with finding quickly your MAXIMUM EFFICIENT POWDER CHARGE for a GIVEN CALIBER, AND LENGTH OF BARREL. The formula does NOT attempt to determine the maximum amount of powder that will "burn" inside a given barrel length and caliber.
"Efficiency" is defined, for purpose of the formula, as the continued similar, or greater, increase in velocity for a given increase in increments of powder used. The "Breaking point" is the " Maximum efficient Powder Charge for a given caliber and barrel. Flintlock rifles can use that powder charge, and shooters can then test loads 10% below to 10% above that recommended powder charge, shooting RBs, to find their most accurate load. Percussion shooters need to reduce that recommended charge by 10%, and then begin testing powder charges, 10 % below that number, to 10% above to find their most accurate load for that gun.
The difference between how you use the formula with flintlock, and with percussion rifles, is that flintlocks LOSE a certain percentage of velocity due to the presence of the Vent at the rear of the chamber. That loss can range from 5-10% of the velocity a similar load of BP fired from a similar caliber and barrel length in a percussion system, depending on the size of the TH( vent).
The Formula was intended to help TARGET SHOOTERS- not hunters--- find their most accurate load for their guns, while keeping recoil to manageable levels. TARGET SHOOTING MATCHES tend to be ENDURANCE CONTESTS, where recoil becomes a factor in deciding the winners and "also-ran's". Hunters rarely fire more than a couple of shots at game during a season, unless hunting small game, where bag limits are generous, and heavy powder charges simply are not needed.
The formula works for what it is- and NOTHING MORE. It has been misrepresented, and misused, HERE, on this forum, by people who have other motives in mind.
I AM UNAWARE OF ANY FORMULA that can give a clue as to the Maximum powder charge that will burn in a barrel of a given caliber and barrel length. When you consider the different burn rates of different kinds of Black Powder, based on changes in the percentage of chemicals used, and the size of the granules produced by different manufacturers, Even attempting to create such a formula would be "SILLY"! Throw in the substitute powders and you now have an exercise in Frustration and Futility.
Phil Quaglino, who is my source of information about Charles Davenport, and the "formula", uses the formula not only in his rifles, but also in his revolvers and pistols. Phil holds or held several National Championship Records in both Rifle and handguns.
For the typical .36 caliber revolver( ie. Colt 1851 model replicas), he recommends using 13 grains of FFFg Goex powder. For the typical( ie., Ruger OAA) .44 caliber revolver, he recommends using 18 grains of FFFg powder FOR TARGET SHOOTING. He uses those same powder charges in his revolvers when hunting rabbits or other small game with BP revolvers, taking head shots, at short ranges, to preserve as much meat as possible. Those powder charge recommendations are based on the "formula".