You want the back end of the vent hole to be about 1/8" in front of the face of the plug. That sounds like a lot, until you measure it. That space allows a place for some crud to build up without interfering with the igniting of powder in the barrel.
White Lightning liners come in a couple of diameters, so choose the one that will work best in your gun, taking into consideration the location of the current vent, the face of the plug, the center of your flashpan, the height of the barrel flat into which you will screw the liner, etc. The liners have fine threads, to increase the amount of threads that hold the liner in the side of the barrel. Make sure you use the tap they send you, or will sell you with the liner for threading the barrel for the liner. Take your time, and do the tapping correctly. Remove excess metal from the inside of the liner- that portion that is in the barrel. You want the liner to NOT extend into the bore, and obstruct your cleaning jag from reaching down to the plug.
Once you have the liner installed, you can back it out, temporarily put the breechplug back in, mark the thread that may( I do say "may") interfere with the liner. Since the plug has more threads than the liner will have at this point, grind away that spot on the threads to create a relief to allow the liner to seat all the way down in the barrel. You won't be removing much metal, and the work should not even be visible from the muzzle. That smooth, flat face you filed will be seen in its entirety.