Charcoal bluing is only blotchy when done by folks who cannot control the process very well.
Mike Lee (?) offers a Rust Blue product. Heat barrel to 200 degrees and apply solution. Card and then immerse in boiling water. Repeat. I guess it is supposed to be more blue than using browning solution and immerse. That turning more black.There are some semantics that need to be clarified to address your question.
Rust bluing usually refers to the process of placing a piece of metal that has been rust browned into boiling water which causes a change in the iron that in turn causes it to turn from brown to a blue/black color. So rust bluing probably followed closely behind rust browning which became more common near the end of the 18th century in America.
There are other blueing techniques that are probably older.
One is temper bluing aka heat bluing aka fire bluing. This is the process of heating a piece of iron or steel in a controlled manner until it reaches the desired temperature and color. A temper blue finish is not very durable.
The other is charcoal bluing. This process places the metal part in a bed of coals and allowing it to heat up until it attains the desired color. The benefit of this process is that a thin layer of forge scale usually forms that provides a layer of protection to the finish and makes it more durable. The drawback it that the finish can be mottled or blotchy.
Temper bluing and charcoal bluing evidently date back a long ways as they easily could have been observed and perfected in a blacksmith forge.
Crooks writes, "I do not think them of that bright lively blue which distinguishes the English and on which I trust you will bestow your most particular attention until your Guns are really of as fine a color as those we have been in the habit of importing when I shall readily pronounce them every way equal."
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