Interesting experiment, and it does illustrate some interesting physics. But it's incomplete.
Yes, electricity does not 'flow through' the bp cyrstals. And yes, (for that reason) does not heat them up. And yes, heat is what is needed to get the crystals to ignite. All that is fine and dandy. Gee, bp must be safe to handle without concern for static electricity, right?
Wrong.
The issue is not the bp crystals, it's other impurities that DO conduct, with significant resistivity, and thus DO get heated up by static electricity. All we need is a small bit of resistive material in the powder to get sufficiently heated by a static electricity spark and, well, the results of the experiment are just a bit different.
So, if the plastic container can generate a spark, and if the powder contains some foreign material with the right dielectric properties, we have the potential for a problem.
I think, anyway. Is that correct?