Sounds like this is a nice piece well worth salvaging.
Sometimes the barrel wedge is not totally clear of the cylinder pin slot, so try very gently tapping with a brass wedge pin. The wedge may appear free but in fact is sticking slightly into the cylinder pin. PLEASE don't use a screwdriver or steel punch on this, use a brass or wooden wedge!
The barrel should pry off with little effort of the loading lever braced against the web between cylinders. If it does not come off smoothly, there is something else wrong ... maybe rust or crud on the cylinder pin. That being the case, try KROIL or another rust penetrant on the cylinder pin, plus the lower spot where the barrel joins the frame (2 pins/holes here), wait a few days, try again.