My 2nd Edition says a .32 loaded with Pyrodex P has the following velocities and pressures:
30 = 1837 @ 12,700 psi
40 = 2039 @ 16,100 psi
50 = 2237 @ 19,500 psi
60 = 2363 @ 22,600 psi
70 = 2488 @ 25,600 psi
As you may note, heavy powder charges with Pyrodex P can generate some very serious pressures that get into the smokeless powder range.
If you were shooting GOEX 3Fg powder in the same gun the velocities and pressures are:
30 = 1940 @ 9,400 psi
40 = 2072 @ 9,900 psi
50 = 2203 @ 10,400 psi
60 = 2238 @ 13,000 psi
70 = 2273 @ 15,500 psi