Well, the current Ruger Old Army Manual says in part,
"Black Powder is usually classified by powder
grain size, with “Fg” being the largest granulation and “FFFFg” being the
smallest granulation normally available. Any granulation within these gradations
could be used in the “Old Army”; normally, however, “FFFg” is the preferred
grain size. Replica black powder such as Pyrodex may be used, so long as
suggested loading data is strictly adhered to..."
It also says,
"It is safe to use as much Black Powder as the chamber will hold, leaving room for
the bullet. This maximum loading is not usually the most accurate loading,
however.
A good starting accuracy load, using a pure lead .457” diameter ball, is 20 grains
of FFFg and sufficient filler (corn meal is frequently used as a filler material) to
seat the ball approximately 1/16” below the chamber mouth. You may find that
some minor adjustment of this charge upwards or downwards is more accurate
in your “Old Army.”
Filler is not required and can be completely dispensed with if the powder charge
takes up at least 1/2 of the cylinder..."
That said, I must warn everyone who is shooting any revolver other than a Ruger Old Army that 4F powder can and will create DANGEROUS PRESSURES if it is used as a powder charge in their Cap & Ball pistols.
Unless they are wanting to relive those thrilling days of yesteryear and experiance the thrill of having their cylinder explode I do not recommend using 4F powder in their guns.