Oooops...sorry musketman & roundball. I should have had an explanation with that remark.
After you shoot, examime the bore of the barrel as much as you can without necessarily shining in a light. If you see small red deposits along the bore...that is a 'bleeding barrel'. Apparently it has to do with the pressure developed with that particular load. If the pressure is too low you will see small green deposits. While working up loads for various muzzle loaders I've made for myself and customers over the years, I've seen this occur.
Pressure, a result of gas expansion and ball inertia, is what we are all really speaking about. Pressure controls the burning rate of powder. The size and shape of the powder granules affects the burning rate as well. If the granules are too large and the pressure too low in black powder, you get large deposits left behind. This is why we're advised to match the powder to the bore size, ball weight and ball/patch fit. When the granules size is too fine the flame can streak through the granules and produce what is close to instant detonation. Powder manufacturers (especially smokeless) solve this problem by making single or double base powders, making the granules of different shapes and sizes and mixing in retardants to control burn rate. I believe that the original Pyrodex was simply black powder with a retardant that made it unreliable for flintlocks.
If you can see a flame out the muzzle of your firearm, you are seeing powder burning in midair.