My guess is that, as others have noted, it is a system design / physics issue and not so much an issue with the choice of barrel steel or how the barrels are made ie 'hammer forged' etc.. Sam Fadala's Black Powder Handbook includes load pressures. The absolute hottest black powder loads are approximately 30,000 psi, with the much more common loads most shooters use running more like 12,000-15,000 psi. Compare that to median centerfire smokeless powder loads at 60,000+ psi and you can see the two are apples and oranges. A brief survey of the structures used to seal the breach to contain 60,000 psi - one, two or three locking lugs; three rings or six rings of steel; a solid breech toggled into place and retained in or by locking lugs. Now compare that to the breech sealing in a muzzleloader, approximately 1/2" of threads. It's possible to strip out threads with a few hundred foot pounds of torque. A threaded connection is not going to safely contain 20 tons of pressure. Additionally, the brass cartridge casing actually restrains a significant portion of the thrust placed on the breech. Add to that the radical difference in pressure curves between smokeless and black powder - and you can understand why everyone is so adamant that for safety considerations the two systems should be kept separated.