I started out testing the revolver at 25 yards from a bench position. I test all my revolvers at this distance for competition .This pistol shoots to the left even off of the bench by about 6 inches. I'm pretty confident that I'll pulling straight through but I'll do more work before I change anything on the gun.
At the same time I started shooting the Pietta I bought a Traditions's Trapper and I have no trouble keepings the shots centered with this pistol. I do like the single shot a bit more, seems to fit my hand better, but I've always been a revolver shooter with smokeless so I want the BP to work as well.
Before I go changing anything else I'll change charge weights and see if that brings them in at all. I'm currently using 20 gr of FFF Swiss with a .454 ball. A few more things to check in the loading data to see what brings them in, but thanks for all the advise so far. I now have more ideas to play with.