If you are going to use Plum Brown (as I often do) yes, you will have to heat the part to a temperature hotter than boiling water (212 degrees F). In fact, it works best if the part is heated to about 275 or 280 degrees before the solution is applied.
This temperature is below the tempering temperatures (400-430 degrees F) for steel so there should be no concern about it's effects on the steels hardness.
If you are really concerned and don't want to take a chanch, you can set the oven to 275-300 and allow the part to come up to temperature in it. Rapidly removing the part and applying the solution will do the job.
The only negative in doing this this way is that the solution gives off fumes which contain Mercury and as we all know, Mercury is not the best thing for our bodies.
These fumes are the main reason I always tell people to use this stuff outside the house.
I suppose if you had the door to the outside open when you apply the Plum Brown it might not cause the dog to go nuts. :grin: Then again, I can't predict what the effects on your spouse will be. :grin: :grin:
(As a side note, the phrase "Mad as a Hatter" comes from the use of Mercury in making hats in the 18th and 19th century. It did effect their minds in most unpleasent ways, but we are talking about rather large doses.)