While I have not done it, I agree the chamfer is probably beneficial.
Keeping in mind the lead ring is just an indicator not a goal. IE, if you shave lead then you have a better idea its going to form a seal and that is (my opinion) they key to No Chainfires.
If you drive a ball back out of a chamber you will see a band on it, depending on the ball size and the chamber, it can be quite wide (.457 in mind is about 1/4 inch) down to .100 area.
Until I contoured it, my 58 Pietta mashed the balls into ugly shapes.
So my take is a contour lets you start it easing the ball into the chamber and less distortion.
Now, the 58 ASP I have came with tapered chambers. No lead ring shaved, but it has a good sealing band. I assume that is how they are made as all chambers on that cylinder are the same.
The 47 Walker has a wider mouth than down further, so it go is tapered though I would not call it chamfered. It has a hair of a shave with a .451 ball (I am playing with ball sizes to see, in that case I am also putting a treated wad in it as I don't know it seals that good and I am not going down in size any more as others have tested it and the .451 is around where chain fires start). A treated wad should act as a flame suppresor if any fire gets past the ball.
I have tested that with wads ahead of the bullets pulling them off on the chamber I am going to fire. You can see the blast pattern on the wads on the adjacent chambers. Despite being in front the blast pattern did not penetrate past the surface much. No where near to coming out the back side. I would not count on a wad alone but with a seal and a wad I think that is safe.
one note, there are people who have other experience and their is to chain fire from the rear. I won't say it can't happen, I don't think its the main cause of chain fire. I know of one person who induced chain fire and it was under .451 that he could make it happen consistently. He was not stupid, he just tested it with an adjacent chamber, prepared for it (gloves I believe and good eye protection).
I was getting some nice just under 2 inch groups at 25 yards with the 47 Walker and the .451 balls.