YOu should check that barrel to see that the back end is square to the bore. That will often eliminate the problem you had. A few strokes with a file to square the back is all it takes. Or, if you have access to a milling machine, create a jig that holds the barrel upright on a pin that fits the cylinder pin hole, and then use an end mill cutter to square the breech of the barrel.
While at it, polish the throat in the barrel, and match the diameter of the throat to the diameter of the chambers in the cylinder, to prevent ball shaving, and to improve accuracy.
Sometimes, the diameters of the chambers of these repros are all over the place, as well as not well centered to the bore of the barrel. My brother had a Remington Repro that was opened up to take .457 balls, in order to get all the chambers to aligne with the bore, and a new barrel put on the gun in the larger caliber. Its a tack driver, now.