I would be motivated to use a hot shot nipple if it solved a specific problem I had. Again, in general these are intended to address ignition problems, and that's a problem I don't have.
You've mentioned that several times, and I understand that. Your logic is sound, considering you don't have ignition problems.
It seem's you have addressed every issue with hammer cup and face including polishing. At this point about the only thing you haven't tried is switching to a different style nipple beyond the two you have.
I've been using the non-vented Knight Red Hot for well over a decade in all my rifles with BP and several different sub's all with reliable ignition and darn few stuck caps. I have re-worked the hammers with particular care for hammer face/nipple contact using a transfer agent like inletting black or simple lip-stick. I keep working the face until I have a full circle of transfer to the face. Any stuck cap usually comes out with a brush of a finger.
What harm will it cause at least trying a different nipple?
I get it, you can't improve successful ignition,, but changing the gas jetting variable may be the answer.
For what it's worth, The Knight Red Hot has a 0.032 orifice,, I use .032 music wire for nipple picks.
p.s. I used CCI Magnum caps for a long time, then switched to RWS 1075