Don't know if anyone read it, but there was a detailed article by "The Bevel Brothers" in a recent issue of Muzzleblasts on this subject.
They reported results of exhaustive tests trying to get a reaction from blackpowder using major compression techniques, including hammering it with a sledge hammer on an anvil, etc, etc, etc.
Hard as they tried with some very extreme attempts, it was impossible for them to get any igniton, combustion, explosion, etc.
Not for a minute should we fail to respect black powder of course, but the stuff is not 'mysterious'...it really is pretty stable...remember, every day of the year, simple cardboard cases containing 25 Lbs of it are routinely being thrown around in and out of trucks, airplanes, etc, being shipped all over the country...I think if it was all that volitile, shipping would be severely restricted if not prohibited all together.