Nipples often need to be fitted for caps. Here's what I do to make sure I have reliable detonation.
Let me warn ya, its not as simple as just replacing the nipple.
Now, many a shooter here will tell you to use BP only. And I agree with them to a certain degree. I have to travel an hour to and an hour from my nearest source of real BP. With Homeland Security requirements, BP sources are drying up and Pyrodex and other substitutes are becoming your only available propellent. So, one needs a hotter source of ignition.
First, make sure the nipple you replace the original with has the proper threads for your gun.
Once the new nipple is installed, quite often your hammer will fall on the cap and nothing happens. The first thing many will tell you to do is to replace your main spring. This may help and again it may not. The most likely cause for this mis-fire is not the mainspring, but an over sized nipple cone.
To cure this problem, you will need masking tape, a power drill, a fine grain knife sharpening stone, dishsoap, a percussion cap and a small amount of water. I generally do this job at the kitchen sink when the ole lady is not at home.
First wrap the threads of the nipple to be honed with masking tape. Two to three wraps should do the trick. Once that is done, chuck the threaded end of the nipple in the power drill. Now put a small amount of dishsoap, mixed with a couple of drops of water, on your stone. Making sure you match the original angle of the cone and with the drill on low, careful not to overheat your nipple, slowly turn the cone side of the nipple on your stone. Don't over do it, keep stopping every so often to use the cap as a guage to ensure a proper fit.
Once you are sure that you have a proper fit, be sure to clean the nipple thoroughly and that the vent is clear of debris. Remove masking tape, dry, oil and install on your gun. I use a little plumber's teflon tape to install mine. If you try this, make sure you don't cover the vent hole.