The guys from the 11bangbang channel on the utoob have made and used obsidian and say it worked well enough for them. I had some mahogany obsidian and after chatting with them made one and it totally sucked. I'll stick to the various cherts and novaculite.
I have knocked out a couple flints from petrified wood and it sucked too. was a special type of petrified wood that i can't remember the name of.
but then i have trouble remembering my own name. its petrified something
I used to practically swim in obsidian when I lived in Oregon; attended the knap-in at Glass Buttes and gathered mahogany at Davis Creek, just south of Lakeview in Nor Cal. Wonderful stuff to play with, but no bueno for flintlocks. Now the harder, opaque dacite might be another matter. Now I am wondering how jasper might work ...