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Obsidian

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I don't think you would get sparks even if it didn't shatter. Like other types of glass, obsidian is 5-5.5 on the Mohs scale of hardness. The hardened steel of a frizzen should about 6.5. Flint, chert, agate are all forms of quartz, which has a hardness of 7. So they are hard enough to scrape little bits off the steel to make sparks.
 
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