Hi!, I don't know but that's a good question, in light of the fact that some claim chain fires occur at the rear of the cylinder; If reaming a cylinder for a better ball/throat/bore fit compromises the safety of the cylinder, is it worth doing? On the other hand I have first hand experience with a brass framed .36 G&G a friend owned that we had fired a lot with lubed chambers and no problems. One day, we were producing an oil well at a remote location and my friend brought out his piece and said, 'damn it, I left my Crisco at home'. We thought what the hell, balls were tight, just like always; same load, same balls, same caps. No lube. Three chambers chain fired, my friend, new to black powder but an accomplished pistolero, almost dropped the gun and spoke some of the most outstanding Spanish profanity I've ever heard. Sure enough, I tried a shot with the remaining 3 loaded chambers and got 2 shots for one trigger pull. Later back home we loaded and fired several cylinders loaded the same way but topped off with Crisco and Bore Butter and no problems. Same load, same balls, same caps. I have never failed to lube my chamber mouths since, except when using the new (then) commercial wads for revolvers. I have never had a chain fire since. I don't know about the ill fitting cap theory; I've fired countless loads with caps I had to squeeze to fit on the nipples, theoretically making a larger gap on part of the cap/nipple interface, with several different types of C&B revolvers and never had chain fire. Perhaps a close study should be made of this phenomenon. I am convinced that with my friend's revolver lube made the difference.