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Extra powder is a diminishing return , cramming 40 grains into an 1860 Army is just fouling the gun up quickerI just saw a video about this.
I only have a 44 so thats the dat I use, but the curve should be about the same just less powder.
The guy did 25,30,35,40gr tests.
The 25 was too little. The 30gr was about right. The 35gr only gave about a 5% fps boost,
and the 40gr loads only changed the fps by 2-3. Using holy black.
I dont see going over 30gr the extra few fps are not worth the powder burnt.
40 is even probably about optimal in a Walker or Dragoon given the little bit of extra barrel and chamber space to burn powder. 50 in a Walker is probably not giving much advantage, there's a reason Sam Colt reduced the cylinder of the Dragoons. I believe the charge with a conical was 40 grains