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Shouldn't it break?

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By the time he dropped the frizzen in it had cooled enough that it wouldn't hurt it. The mixture he described (without the ice) has been used by blacksmith's for a long time, it's called super quench and if he dropped the frizzen in while it was still red hot it probably would have hardened it without the Kasinet.
Super quench has a couple more ingredients like Dawn dish washing soap and Jet Dry but the main ingredient is salt. It will harden low carbon steel to some extent.
 
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