Assuming your sights are tight -
You should shoot from a rest at 25 - 50 yards,
firing 5 shots each from a range of powder charges.
Start with 50 grains and go up 5 at a time to 90 (if you guns maker allows it)
using .490 and .495 roundballs
with patches from .01 - .015 - .02.
As examples, I had a Pedersoli Tryon .50 with 1-48 twist that would shoot a cloverleaf at 50 yards, using .490 AND .495 balls (i forget the charge i used, i think 60 grains). It just wasn't picky about the load. No cleaning between shots.
Currently I have a TC Hawken with a Green Mtn. 1-66 .50 barrel. At 50 yards and 75 grains Pyrodex RS, .495 scrap lead ball, .018?? ticking patch (home cut, about this thick), spit lubed (i'm cheap and drool easily
), it shot 6 shots in a group the size of a musket cap tin. But go up or down 10 grains and the group goes pieces with flyers 6" away to each side.
You will have to experiment. It can be frustrating. Once you have a tight group st short range, then start moving back.