Silverfox: Actually, I worked on this a year ago for another question, actually weighing a volume of powder on my scale using both 3Fg and 2Fg powders. If you had asked me a few years back what this answer was, I would not know without stopping to do the checking with my powder scale. That question was how accurate was a powder " dipper " as used for loading shotguns, vs. using an adjustable measure to throw the charge. I found the dippers a lot closer to throwing both the indicated shot charges, and the powder charges, using 2Fg powder, than I had expected. The shot charge works fairly well with #6 shot, but begins to vary away from the indicated loads marked on the outside of the dippers as you increase or decrease the size of the shot being measured.
My recommendation is to check your own measure. You can use an adjustable powder measure to throw both powder and shot, but if you are going to throw anything larger than #5, or smaller than #7 1/2, I think you should check your measure against a scale, and MAKE A MARK, according to the load you want to throw, given the size of the tube for the measure.