DON'T throw away the Plum Brown. All you need to do is heat that barrel up, after degreasing, before putting on the solution. The bare spots can be from impurities in the metal used to make the barrel. It happened on a 12 ga. double barrel shotgun I put together, and I had to go back and really heat up some of the patches to get them to take the solution, and brown. Today, I defy anyone to find where those patches are. I can show you, but finding them yourself will take a good eye, and lots of experiencE browning barrels to see them.
Just get out a propane torch and heat up the areas that are resisting the process, and swab on the solution while the barrel is hot. Do it in open air, and don't breathe the fumes. I used needle nosed pliers to hold a cotton swab to put the Plum Brown on the barrel, at arm's length, and it worked fine. I used a coat hanger run through a tang screw hole to hold the barrel up hanging off my garage door rail.
When you put the solution on when the barrel is hot, steam will rise almost instantly. And, there will be a yellowish residue on the barrel. It dissolves with more of the solution, and comes off later with plain water, so don't worry about it. Just keep reapplying the solution until you get the color you want. Let the barrel cool for an hour our so, then wash off the residue, and do a good inspection of it in natural light. If you find areas that need more color, degrease it again, suspend it from you coat hanger hook, and heat it up to put on more solution.
I have a deep chocolate brown on my barrels that have drawn nice comments from several shooters over the years. When they find out how I put the Plum Brown on, and they saw how durable the brown finish is, compared to their efforts, they head home to try it again my way.