You only want to break the sharp edge on a chamber mouth as to much chamfer allows more lateral gas escapement at the gap.
Of the dozen cappers I have, I've never have had a cylinder with mouth chamber's with any burrs or sharp edges left by the factory that impeded seating a ball, not that they don't or have ever existed. Ifin a shooter would want to chamfer the mouth a bit it should be just to take the very sharp edge off if any exist and no more. A ring of lead isn't any written requirement for shooting but an indication that the ball is entering the chamber with a tight fit. I've recovered dozens of balls shot into snow that have no damage but show sort of a flat spot on the sides of the ball where it was swagged into the cylinder and shot down the rifled barrel. I use .380's in 36 caliber, .454's in 44's, and .457's in a ROA. All tight fit in the chambers, no chain fires, no ball movement when other cylinders are fired, and use tight fitting Remington #10 caps on the nipples. In 51 years no issues or chain fires. I do use a lubed felt wad also and have no issues with barrel residue, after alot of shots, clean as the proverbial whistle.
No, that wasn't what I meant. On an unmentionable revolver the chambers are chamfered to facilitate the use of a speed loader.
so, on a CB revolver it makes since to do the same on the feed end to help when seating a ball.
The back end of the unmentionable revolver chambers were chamfered way before speed loaders came about. They were chamfered so as to make cartridge loading faster/facilitate without any bullet tip hangups when loading by fingers.