galamb said:Sorry, didn't address your question about how it's determined.
The only way to specifically address your personal rifle is to have it chronographed with different powder charges - mine was measured at 15 ft from the muzzle and the results were plugged into a ballistics calculator to extrapolate the results at various distances.
You don't have to go to that extreme. Often times data collected by others using a similar rifle/barrel will be "close enough" to apply - likewise, sources such as Lyman publish data that will also be close enough to help you determine if using say 100 grains is significantly better than 80 grains (or whatever).
For "me" black powder is expensive ($34/lb including tax) and I have to drive 3 hours, one way, to buy it.
Shooting 80 grains I get about 90 shots per pound. If I move up to 110 grains I only get about 65 shots per pound.
And for shooting all that extra powder I only would get 10% more retained energy = NOT WORTH IT, in my case...
People make a mistake in assuming that at the velocities we run that energy is a good guide for killing power. Its not. Its not really valid for anything but gives the small bore smokeless crowd a reference. For example a 243 will produce a lot more energy than a 45-70 BP load will. But if I have a bear with an attitude at close range the 45-70 is a better choice.
It is difficult to increase the killing power of a RB with velocity. Since BP is velocity limited energy is not a good guide. Ball diameter is the key. Also given a pure lead ball they will usually penetrate similarly in tissue (bone is another matter) since the velocity is the same and their ballistic C is similar though again a large ball with is better density will penetrate a little better. On deer in my expericence a 50-54-67 cal rb all penetrate about the same. However, while the 50 and 54 both kill well they are not in the same class as a ball weighing twice what a 54 ball does.
The reason for higher velocity, say 1800 fps vs 1400 at the muzzle is TRAJECTORY. The 1800 load will shoot FAR flatter than one at 1400.
This is the great advantage of shooting more powder. If shots are taken at less than 50-60 yards a 45 caliber with 45-50 grains of FFF will kill deer well if it shoots OK. So if shooting from a tree stand at pistol ranges lighter charges will work if the accuracy is OK. If the hunter is in the west or someplace where the shots are likely to me 100+ then a load of 65-80 is better since it will shoot flat enough to 100-120 to require no hold over from the point of aim for 40 or 50 yards.
Dan