My inquiring mind found some good old info on acid etching after I asked the question on here. My newly acquired October 1965 issue of MuzzleBlasts magazine has an article about the subject.
Not giving a time period the article states "The old time riflesmiths, before metal stamps came into use, etched their names on their products with acid."
The writer, Brass Tomahawk, goes on to tell how it was done by masking the surfaces with wax, then removing the wax, (he recommended a non-writing ball point pen), where the etching was wanted. The wax protected the surrounding metal. He points out that any mistakes can be corrected, even by removing the wax and starting over, up until the moment the acid is applied, with a medicine dropper. The acid used is either nitric acid or iron chloride(?). These were readily available in 1965, I don't know about today.
Just one of the many interesting articles I've found in my growing collection of MB magazines. I wish I had starting looking for them years ago!