Mark Meredith said:
I found some interesting discussion below on barrel lengths and their relationship to % of powder burned during a discharge. Interesting reading. Is there a difference between FF and FFF in burn rates? Does FF require a longer barrel because it burns a little slower?
Thanks
BP is a surface burning propellant. So the greater the surface area the faster the burn.
From what I have been told by an actual expert in BP FFFF is twice as fast as FFF is twice as fast as FF is twice as fast as F. But this is a GENERAL rule. Close but not absolute.
Burn rate can also vary between brands, between lots of the same brand and even in the same can of some powders. Though this last has been largely corrected in the last 5-10 years.
This does not mean FFF makes twice the pressure of FF so don't jump to conclusions.
There are other factors related to manufacturing and materials that effect burn rate. Milling time quality of the charcoal and other components and the amount of Potassium Nitrate used. "Sporting" grade powders of the past and I think Swiss today uses 76% saltpeter. A high polish on the grains (not graphite) as in Swiss, will actually somewhat retard the initial burn rate but its slight. But apparently enough to be measured by breech pressure.
I would not worry about burn rate related to barrel length. This would require a lot of testing and as was shown in Lyman's first BP loading manual, variations in powder from lot to lot (can to can) can offset any conclusion based on the grain size used.
I do not subscribe to the notion that its possible to calculate how much powder a barrel will burn based on the capacity of the bore.
If so the bench gun line at Friendship would likely erupt in a fast fire from all the ejected unburned powder some of these shooters use a LOT of powder for the bore size. Far more than will burn according to the formula I have seen.
Dan