There is NO WAY chainfire is caused by no lube over the chamber mouth.
TURN ON YOUR BRAIN AND THINK ABOUT IT:
1) 100% OF THE TIME, ALL OF THE LUBE is melted off ALL the chambers with the FIRST shot.
In other words, and to make it simple:
AFTER THE FIRST SHOT THERE IS NO LUBE OVER ANY OF THE CHAMBERS.
2) When the proper size ball is used, you shave a ring between 0.002 to 0.004 inch off the ball. The ball to chamber wall clearance is 0.0000...inch/ZERO/NONE.
In order for the heat or a spark to reach the powder from the chamber mouth there has to be a gap between the ball and the chamber sides.
3) 100% of Chain Fires are caused by loose or missing caps on a loaded chamber.
(a) A loose cap or caps CAN be and ARE knocked off by recoil.
(b) You get sparks and heat out of the nipple when you fire. Yes, enough to cause a chainfire if the cap(s) are loose and/or missing.
To prevent chainfire you have a couple options:
(from least practical to most practical)
1) Only load one chamber at a time.
2) Put a dollop of grease or lube over each cap. (Yes. This is as messy and a bigger PIA than it sounds)
3) Pack dry uncooked Cream Of Wheat or Malt-O-Meal cereal over the ball.
4) USE SNUG FITTING CAPS AND MAKE SURE THEY ARE FULLY SEATED.
I did not use over powder wads or cards.
When shooting blanks (powder only, no ball) I packed uncooked Cream Of Wheat over the powder.
I did not pack Cream of Wheat (or Malt-O-Meal) over the ball when shooting live rounds.
During that ten year period, I had exactly ZERO chainfires or hang-fires.
I shot both the Colt open top, and Remington solid top reproduction revolvers.
They were loaded the same way.
First of all, you must be one of those keyboard-cowboys who communicates differently with people over a forum than if you were face-to-face with them.
Telling me to use my brain infers that I may not be intelligent enough to know what I'm talking about.
I like to have a certain degree of anonymity on these forums for reasons that I won't get into. With that said, you would have thought more carefully about your
"turn on your brain on" remark before you made it if you knew what I do for a living. Because I want to protect my identity and privacy, I won't tell you what I do. Besides, my employer would not appreciate it.
So, I'm not an idiot.
You state that you have shot various cap & ball revolvers for a ten year period with zero chain fires. Well, I've been shooting cap & ball revolvers for well over 40 years.
It wasn't until last year that I witnessed a couple of chain fires and experienced one for myself. So give yourself another 30 years and you might have one.
IMHO, the reason for chain fires is for both a spark entering an unfired chamber through either the mouth or an uncapped nipple. In my friend's case, I would say that it was definitely because of a spark entering the chamber mouth and getting past the ball.
I believe we can eliminate the uncapped nipple scenario as he's in the habit of pinching the caps before putting them on. I've also shot with him a lot and have never seen an un-fired cap depart from a nipple. So I don't think it fell off on both incidents.
We both use the same lube and it stays in the chamber after the first round fires. He simply forgot to lube the chambers and freely admits to that. Furthermore, the chain fires stopped when he made a conscious effort to lube the chambers. So there is a good possibility that lack of lubricant was the culprit.
In the case of my LeMat, I was trying a heavier charge with paper charges. The caps also fit tight on the LeMat. They haven't fallen off on it yet. And I've had that revolver ever since Navy Arms first offered it.
That LeMat also uses a .445 round ball. When I first got it, the .451 balls were extremely tough to load. In fact the loading lever bent twice on me. Navy Arms repaired it both times. After measuring the chambers I determined that a .445 round ball was the correct diameter. To everyone else that is shooting .451 balls out of your LeMat, that's great and I won't argue with you. You are the one that knows what works with your revolver. All I know is they sold me one that takes a .445 round ball and voilà, no more bent loading levers.
Now back to the weird chambers on my LeMat. After I had the chain fire in it I looked at the chambers and noticed that as it got closer to the nipple end that it got tighter. In that area of the the chamber where the ball is seated it is very tight. Closer to the mouth of the chamber is where the ball was with the heavier charge.
Even with the lube in place, I got a chain fire. By the way, I was also using a paper charge with ball already lubed. So I didn't have as much lubricant as if I had loaded with loose powder and ball. I've went back to a lighter charge, loose powder and ball without any problems.
IMHO, I don't think there is enough data, in the form of high-speed videos or photographs to say for certain what
one culprit, over the other, of chain fires are.
Empirically speaking, we know of only two possible avenues that a spark can enter the chamber of the revolver causing a chain fire. I don't have to turn my brain on to realize that.
What this discussion gets down to is; what is the cause of a chain fire? It is either...
1) Only a spark entering the chamber through an un-capped nipple.
2) Only a spark entering the chamber past a loaded ball.
3) Either a spark entering through the un-capped nipple or past a loaded ball.
IMHO, I think it is number 3.
You also make the definitive statement;
"AFTER THE FIRST SHOT THERE IS NO LUBE OVER ANY OF THE CHAMBERS."
Perhaps you and I are not using the same lubricant. In my early days of shooting cap & ball revolvers I used Crisco like a lot of us. With that lubricant, I agree with you entirely. It all comes off with the first shot.
You don't say what type of lube that you use, but if you don't mind a little experimentation you might try a 50/50 mix of beeswax and vegetable (or olive) oil. During colder weather I use the 30/70 mix of beeswax/oil. It stays in place on every un-fired chamber of my revolver.
Like I said, I've been shooting black powder firearms for over 40 years but will admit that I can always learn something new from anyone; even you, if you ever have something good to say.
Now I would suggested that you exercise a little discipline by engaging your brain before you type out bold and insulting statements to people that you don't know. Then, perhaps, your comments might be taken a little more seriously.
Please have a great day.