To understand why smoothbores lose their accuracy beyond about 75 yds, you have to understand how poor an aerodynamic body a round ball is. It sheds velocity very quickly, and this is only overcome slightly by spinning the ball in the air by rifling a barrel. Without any spin, the ball comes down through the Transonic zone at between 1100fps, and 1400pfs. The buffeting that occurs as sign waves speed past the round ball creating turbulance that moves the ball one way or another in this velocity range is one of those laws of nature you can't do much about. Spinning the ball makes the ball fight the friction of the air some, and a spinning ball loses velocity slightly slower than one that does not spin. The advantage to shooting a round ball that is spinning is that it maintains it direction of travel better when those waves and the vacuum that follows the ball either stop, or come forward past the nose of the ball during flight. This is why the spinning ball remains accurate even when its velocity goes below the speed of sound. In fact, slug gun shooters, shooting conical bullets, instead of RB, will try to keep their bullets at a velocity under the speed of sound, if shooting at long range targets, while those shooting at targets of 60 yds and shorter, will often use such a stout load that the bullet, or ball, is still going more then 1400 fps when it hits those shorter range targets. For instance, Chunk Gun shooters who usually shoot at targets set at 50 or 60 yds, often use 38-50 cal rifles, shooting RB, but with velocities at the muzzle reaching more than 2000 fps! What goes fast, also slows down fast, so by the time these balls get to the 60 yd target they have shed more than 25% of their velocity.
Choosing whether to shoot a smoothbore, or rifled gun for hunting depends almost entirely on where you intend to hunt, what you intend to hunt, and how good a hunter you are. If you can kill a deer shooting a shotgun slug out of a smoothbore shotgun, then you can kill the same animal with a smoothbore, large caliber BP long gun. If shots are going to be over 75 yds, you want to use a Rifle, regardless of caliber. The heavy RB loads used in smoothbores will kill at many times the 75 yds we talk about here, but you want to be able to deliver that ball accurately so you can make a clean kill. You would not want to volunteer to be hit at 500 yds with a .600 cal. 325 gr. lead round ball fired from a 20 gauge smoothbore. But the chances of someone actually hitting you at that distance, even when they aim the gun at you, is in the realm of bad luck! Hope that answers the question in terms you better understand.
Paul