Using the same powder charge volume as your bore diameter is much easier than crunching the numbers.
Indeed, that's a good overall method. Works on .50 and .54 calibers for a fact.
However, that puts me over the maximum on my .32 Crocket rifle, which is 30.0 grains. Perhaps that's the odd duck rifle?
Then again, that's for 3F, not 2F, so that might make the difference, eh?
Not stating which method is correct for a beginning powder charge. However, when I used the formula Fish posted, for my .32 Squirrel rifle, it equates to 19.157 grains. 20 grains just happen to the the recommended charge for best accuracy, which it is.
Using the formula Fish posted for my .54 I came up with 95.87 grains. Round to 96 grains. My guess is most folks use 2F in .54 caliber.
Indeed, ball park figures.