Perhaps you should read your reference more closely.
"Now on to the mystery behind the letter 'F'. The letter 'F' stands for "Fine" and dates back to the time when the grains were designated F or C (for "coarse" grains). The number of times the letter F occurs in the powder grade shows the average size of the powder grains. The more times the letter F occurs in the name, the smaller the grains. What this means is that the size of "FFFg" grains are smaller than "FFg" grains, and "FFFFg" is even smaller than these two. When black powder is manufactured, the grains are sorted through sieves of standard sizes and classified that way."