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zimmerstutzen said:the problem with all these substitute projectiles is the same as the problem with non-lead shot for waterfowl. The specific gravity isn't dense enough to carry the balls energy like lead. A tin/bismuth ball will drop even more of it's energy than lead at 100 yds. Punch all the holes in paper that you want, but the issue is game and penetration. I am primarily a target shooter and frankly could care less how slow a ball punches through a piece of paper as long as the group is small. But for hunting, some of these substitutes may as well be made of styrofoam because they won't be worth crap at 100 yds for hunting unless the material has a specific gravity close to lead. There is such a material, but the cost would be prohibitive. Gold.
The lighter weight on iron balls would make big smooth bores attractive. Something like a Bess with a rear sight could be a winner.