I have used leather wads with shot loads in a smoothbore, but not recently. There was an article mentioning this practice in a back issue of Muzzle Blasts, from the late fifties or early sixties. I'll look it up.
Leather wads worked great for me. I was never very scientific about it, but just used whatever scraps of heavy belt or harness leather were available.
A 5/8" arch punch cuts perfectly sized wads for 20 gauge. I don't know about the other sizes. What you want is a wad diameter somewhere around .010" larger than bore size. Arch punches are not cheap... Last time I bought one, I think I paid $35 - $40 for it. The larger sizes cost more than the small ones. I believe they come in fractional sizes in increments of 1/16" (.0625"), as well as metric sizes. I don't have a link handy, but if you look up Campbell-Bosworth tools, you should find a good selection of fractional and metric punches. You can calculate the size you need.
I don't want to vector too far off topic, but there was an article in Muzzleloader magazine a few years back by Mike Nesbitt in which he described cutting wads from wool blanket scraps. After cutting the wads, he would drop them in a pot of melted tallow, which the fabric would soak up almost immediately. He then lifted the wads out, I guess with forceps, and spread them out to cool. I haven't tried this. Sounds like a good way to keep your bore lubricated while shooting, not to mention your hands.
Best regards,
Notchy Bob