I've been studying about everything I could find on the net about paper cartridges for some weeks now.
Here a few sparse thoughts and some questions.
I'm talking about combustible paper cartridges for revolver, not the paper cartridges used for muskets or single shot pistols which were to be torn to pour powder into the barrel.
All the examples of vintage cartridges of this kind I've seen where more or less tapered.
I've pondered quite a lot about this, and I believe there's more than meets the eye in this detail. The obvious function of the taper is to facilitate insertion into the cylinder chamber. But I think this shape serves also another, much more relevant purpose. A cylindrical cartridge would just be seated home by the rammer.
When the hammer hits the cap, the fire jet it produces has to burn through the paper at the bottom of the cartridge. If it's single layer, no problem, but stacked, compacted paper is quite resistant to burning. So, if you have a cylindrical cartridge which has been closed by turning the paper (like many tutorials show) or by folding and gluing, you may get misfires.
A tapered cartridge, on the other hand, would be crushed in place, the smaller end bursting under the pressure applied by the rammer, releasing the powder and greatly facilitating ignition.
This is a mere hypothesis, which I plan to investigate in a more accurate manner as soon as I have some time available, using a cartridge mock up loaded with some inert material (cream of wheat sounds good).
Nitrated paper, that is, nitrocellulose used to build the paper cartridge, surely would burn completely, but should some remain trapped between ball and cylinder, could it enhance the chance of a chain fire?
Paper soaked in saltpeter doesn't sound so good to me. I thought it was, some time ago, but now it seems less and less viable.
First and foremost, I believe the solution should not be a saturated solution. As I suspected and others have confirmed on this same thread, paper soaked in a saturated solution of saltpeter would have much more of the stuff than it's needed to burn the paper.
I've made various experiments making slow match which I then used to ignite my coal forge with flint and steel. Saturated solution sputters and leaves residue. A milder solution produces a complete burn yet is cleaner.
Anyway, the chance that partially burnt paper remains smouldering in the chamber could be fairly high.
Having built many flying models with my father when I was young, I believe that onion skin paper with paper dope can be the way to go. This stuff burns fiercely and very quickly when ignited. Moreover, paper dope should give the cartridge added stregth.
Right now I'm at a loss about where to buy it. There was a big store which sold everything for model planes but it's been out of business for some years now. I'll have to look around. Next week I hope I can go shooting my Colt Walker. I've readied three dozens paper cartridges with 40 grains of FFFg powder in onion skin wrapping for testing. Let's see how they perform.