Its been my experience that alloy leads don't come out round, from molds that will cast round pure lead balls. I am not sure of the reason, other than the variations in the alloy mix. It may be that I need to stir the lead on the pot frequently, instead of leaving it alone, once I have skimmed the dross off the top. It was very discouraging. The lead used was scrap picked out of the backstop at the range. It included lead from the core of copper jacketed bullets, WWs, probably some pure lead, as well as alloy pistol and rifle bullets others had made. The Balls were HARD.
I used the balls in a pistol, anyway, because even enlarged, they were still small enough to require a fabric patch around them. Accuracy at pistol range( 25 yds.) was as good as I could hold that .62 cal. smoothbore.
Using pure lead for casting balls, even for a smoothbore, takes a lot of variables out of the process. To answer the poster's questions, however, I agree with everyone else that there is NO NEED to use pure lead for the balls.
My concern is related to using unknown alloys in lead, that make the lead even harder than old WWs. For instance, when the same scrap lead was cast into pistol bullets, we had the same problems with size, and hardness. Using a bullet sizing die, some bullets went down easily, and others required 3 times the force to get them through the sizing die.
I didn't have a lead hardness tester at the time, but the experience with the sizing die told us that there was problem with the mix. There was also a wider variation in the weight of both balls and bullets cast from the scrap unknown alloy mix lead. When we started to use ONLY wheel weights, for instance, our weight variations were much smaller, and the bullets run through the die required more consistent force.
We stopped scrounging lead from the backstop at the range as a result of these experiences. Later, I scrounged pure lead from the RR ties used to back the targets at my MLer club, since we were all shooting either pure lead, or darn close to pure lead. Modern rifles were not allowed on the range.