Depending on caliber, the answer is usually NO. At 100 yards, the RB has dropped down through the sound barrier for both smoothbore, and rifled guns. If it retains velocity, it will be in the rifled barrel that causes the ball to spin, which helps it cut through the air it is hitting on the way to the 100 yard target, but the margin of improvment is small.
A round ball fired out of a smootbore barrel is basically a ' knuckle ball " throw by a major league pitcher. It has no " spin ", It flys only so far and then starts doing different things, just like a knuckle ball will drop suddenly out of the the flightpath so that the hitter swings over the top of it and either misses the ball all together, or tips it down into the dirt in front of home plate, for an infield " OUT ". After about 80 yards the Round ball loses velocity fast, and groups sizes open dramatically. That does not mean that some guns, in some calibers don't shoot fairly respectable groups at 100 yards. Not at all. That is the fun part about working up loads for smoothbores. You can get better groups at 100 yards. We are not, however comparing those groups with what you should normally expect from a rifled barrel shooting the same sized ball.