The core fact is that the smaller the grain the faster and higher is the peak pressure. How much that will affect the safety of the gun is a matter of debate. It is simply a risk that is avoidable without affecting the use of the gun. How big that risk may be is uncertain in the individual case.
I have acquired a 0,320" Ardesa Crockett rifle. The twist at 1:48 allows for a patched ball to use an accurate load as light as one desires. With a conical the twist needs a much larger load to get the same revolutions per second for the same stability. Even with a large load in such a small bore I judge that it should manage the extra peak pressure to obturate the short bullet and exit it at a suitable high velocity were I to use 4F powder. I would be concerned (my judgement) in a larger bore that extra pressure and faster pressure rise is not so containable. Others may judge differently.
I have read extensively on the enormous amount of research done by governments, manufacturer and academics on the analogous work on heavy artillery in the latter 19th century and they had catastrophic problems working with ordinary coarse grained black powder. These were solved with a huge improvement in performance by swapping to very large fist sized blocks of back powder and even more with the even slower burning brown/cocoa powders using partially carbonised charcoals. How analogous that may actually be to small arms is open to question but it demonstrates a hazard. Whether that hazard is an actual risk I am not qualified to argue.
You are all, I trust, intelligent rational adults so must make up your own minds but I would be lacking in my duty to others if I did not make my concerns known. I think the hazard exists. I think the risk is small. But I do think the risk is proportional to the bore with a normal charge. No one is obliged to agree with me.
The smaller the bore the higher the pressure and for longer than a larger bore
In a smaller bore the surface area for the propellant to act on demands more work and for longer which often translates in much higher muzzle velocity than a larger bore.
Basic principles of hydraulic systems can demonstrate this.
In a larger bore the propellant has more surface area. It is there for easier to lift off. That coupled with quickly developing volume increase actually drops or holds pressure peaks low and short.
This is easily demonstrated by nitro powder charts and applications to shotguns. Much slower or retarded powder is needed for a 20g compared to quite fast powders for a 12g.
Whilst there is no direct comparison with black powder and nitro the underlying physics of a smaller piston arrangement compared to a larger piston arrangement is that the lesser will need more pressure to return any work.
So in small arms, not cannon or artillery, no relationship what so ever, it matters not it being a fine granulation. We know this because it is not banned from such use. It is not banned from such use because no one has demonstrated it causes damage or is dangerous.
Assuming proves nothing. I use to ride motorcycles with a gas tank next to the families jewels. Not once did I contemplate them getting flamed so thought that putting diesel fuel in the tank would be safer!
My own personal tests with 1f in shotguns resulted in lousy patterns and very low velocity. In numerous guns I had to tip far more in than the volume of the shot load to get some velocity but the patterns were lousy. This was with 12&.75". 20g was slightly better but not enough for me to recommend it.
Nope 3&4f for me all day long thanks.
B.