Some shooters didn't know they were using alloy ball until they encountered truly pure lead ball.
:idunno:
Others, as reported, used what they could find..., some harvested spent lead slugs from pistol ranges and re-cast them while not knowing that pistol bullets are mostly alloy, and others used harder lead recycled from applications that required harder lead..., and some used old wheel weights or even linotype. :shocked2:
Folks found problems not in accuracy but in loading . Those who had been using soft lead, when trying by accident or by design an alloy lead, often found the patch they had been using was too thick for the alloy ball. Then..., when switching to a thinner patch some found it too thin as they got burn through or other problems, so in those cases..., they had to switch to a smaller diameter mold when making ball from lead alloy. (for example a fellow who loves .535 ball might have to switch to a .530 mold if using wheel weight alloy to cast balls for his rifle.)
The other situation is terminal performance. Not a factor on paper, although the point of impact at long range might be higher with an alloy ball because it might be sufficiently lighter that it's moving faster, so doesn't "drop" as much.
THEN there's what the ball does to a large game animal. Some want the soft lead for it may deform on impact..., and others may want the ball to hold it's shape as would the harder, alloy ball. This is because they want the ball to penetrate as far as possible, and think that in their case on that particular type of animal, a round ball deforming is increasing it's loss of speed within the animal, as it flattens and increases the surface area relative to the wound-channel that it is creating.
For me..., if it shoots straight, and hits where I've lined up the sights (shooting straight gives you a nice grouping of shots, shooting straight where I've alined the sights puts that group where I wanted the group of shots :wink: ) and the bullet has sufficient speed to humanely dispatch the deer..., I don't think it matters to the deer if the ball says .530 or deforms to .620 diameter.
Whatever works for your rifle, for one of the quirks of this game is that the rifles often don't shoot similar combinations when all the "facts" say they should..., it's going to be more important I'd wager, for you to get some regular, successful, range time, rather that what type ball, pure or alloy, you're launching. Probably more true for the guys who use them smoothbores.
LD